Volatile sulfur-containing compounds (VSCs) play an important role in wine aroma conferring at high concentrations unpleasant odors but also participating positively at low concentration. A large number of VSCs are formed at different stages of winemaking and storage. To monitor this phenomenon, a HS-SPME-GC-MS/MS method has been developed. The method is proposed in order to quantify 27 different sulfur-containing compounds. SPME extraction was performed using a carboxen-polydimethylsiloxane (CAR-PDMS) fiber, which resulted the most effective fiber coating. Time and temperature extraction conditions were optimized using response surface methodology. The selectivity and sensitivity of the method were considerably increased using triple-quadrupole in multiple reaction monitoring (MRM) mode. The number of VSCs analyzed in a single run was higher than in any other method previously reported using single-quadrupole MS or other detectors. The overall process was successfully applied to identify and quantify sulfur compounds both in white and red wines

Slaghenaufi, D.; Tonidandel, L.; Moser, S.; Roman, T.; Larcher, R. (2017). Rapid analysis of 27 volatile sulfur compounds in wine by headspace Solid-Phase Microextraction Gas Chromatography Tandem Mass Spectrometry. FOOD ANALYTICAL METHODS, 10 (11): 3706-3715. doi: 10.1007/s12161-017-0930-2 handle: http://hdl.handle.net/10449/45612

Rapid analysis of 27 volatile sulfur compounds in wine by headspace Solid-Phase Microextraction Gas Chromatography Tandem Mass Spectrometry

Slaghenaufi, Davide
Primo
;
Tonidandel, Loris;Moser, Sergio;Roman, Tomas;Larcher, Roberto
Ultimo
2017-01-01

Abstract

Volatile sulfur-containing compounds (VSCs) play an important role in wine aroma conferring at high concentrations unpleasant odors but also participating positively at low concentration. A large number of VSCs are formed at different stages of winemaking and storage. To monitor this phenomenon, a HS-SPME-GC-MS/MS method has been developed. The method is proposed in order to quantify 27 different sulfur-containing compounds. SPME extraction was performed using a carboxen-polydimethylsiloxane (CAR-PDMS) fiber, which resulted the most effective fiber coating. Time and temperature extraction conditions were optimized using response surface methodology. The selectivity and sensitivity of the method were considerably increased using triple-quadrupole in multiple reaction monitoring (MRM) mode. The number of VSCs analyzed in a single run was higher than in any other method previously reported using single-quadrupole MS or other detectors. The overall process was successfully applied to identify and quantify sulfur compounds both in white and red wines
Volatile sulfur compounds
MS/MS
Multiple reaction monitoring
SPME
Response surface methodology
Wine
Settore CHIM/01 - CHIMICA ANALITICA
2017
Slaghenaufi, D.; Tonidandel, L.; Moser, S.; Roman, T.; Larcher, R. (2017). Rapid analysis of 27 volatile sulfur compounds in wine by headspace Solid-Phase Microextraction Gas Chromatography Tandem Mass Spectrometry. FOOD ANALYTICAL METHODS, 10 (11): 3706-3715. doi: 10.1007/s12161-017-0930-2 handle: http://hdl.handle.net/10449/45612
File in questo prodotto:
File Dimensione Formato  
10.1007%2Fs12161-017-0930-2.pdf

solo utenti autorizzati

Licenza: Tutti i diritti riservati (All rights reserved)
Dimensione 706.62 kB
Formato Adobe PDF
706.62 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10449/45612
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 21
  • ???jsp.display-item.citation.isi??? 20
social impact