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EnglishEfficient power technologies such as high temperature fuel cells demand ultra-low concentrations of contaminants in the fuel feed e.g. < 1 ppm(v), imposing stringent requirements on fuel clean-up technology. Proton transfer reaction-mass spectrometry (PTR-MS), being fast and suitable to measure ultra-low concentrations can be an optimal tool for the characterization of clean-up methods. It is exploited here for the simultaneous measurement of breakthrough curves of biogas filters loaded with a mix of compounds that simulate biogas pollutants. The sorbent materials are able to efficiently remove propanethiol and butanethiol and to a lesser degree methanethiol and hydrogen sulfide. Carbon disulfide and dimethylsulfide were the compounds that elute from the filters. These results support the development of set-ups for the cleaning of real biogas from the Organic Fraction of Municipal Solid Waste (OFMSW) and its use for Solid Oxide Fuel Cell (SOFC) feeding
Papurello, D.; Schuhfried, E.; Lanzini, A.; Romano, A.; Cappellin, L.; Märk, T.D.; Silvestri, S.; Santarelli, M.; Biasioli, F. (2015). Proton transfer reaction-mass spectrometry as a rapid inline tool for filter efficiency of activated charcoal in support of the development of Solid Oxide Fuel Cells fueled with biogas. FUEL PROCESSING TECHNOLOGY, 130 (1): 78-86. doi: 10.1016/j.fuproc.2014.09.042 handle: http://hdl.handle.net/10449/25072
| Citation: | Papurello, D.; Schuhfried, E.; Lanzini, A.; Romano, A.; Cappellin, L.; Märk, T.D.; Silvestri, S.; Santarelli, M.; Biasioli, F. (2015). Proton transfer reaction-mass spectrometry as a rapid inline tool for filter efficiency of activated charcoal in support of the development of Solid Oxide Fuel Cells fueled with biogas. FUEL PROCESSING TECHNOLOGY, 130 (1): 78-86. doi: 10.1016/j.fuproc.2014.09.042 handle: http://hdl.handle.net/10449/25072 |
| Internal authors: | |
| Organization unit: | Food Quality and Nutrition Department # CRI_2011-JAN2016 |
| Authors: | Papurello, D.; Schuhfried, E.; Lanzini, A.; Romano, A.; Cappellin, L.; Märk, T.D.; Silvestri, S.; Santarelli, M.; Biasioli, F. |
| Title: | Proton transfer reaction-mass spectrometry as a rapid inline tool for filter efficiency of activated charcoal in support of the development of Solid Oxide Fuel Cells fueled with biogas |
| Journal: | FUEL PROCESSING TECHNOLOGY |
| Issue Date: | 2015 |
| Scientific Disciplinary Area: | Settore CHIM/01 - Chimica Analitica |
| Keywords ENG: | Proton transfer reaction-mass spectrometry (PTR-MS) Biogas Solid Oxide Fuel Cell (SOFC) Volatile organic sulfur compounds (VOSCs) Desulfurization Filter breakthrough curves |
| Language: | English |
| IF: | With Impact Factor ISI |
| Publication status: | Published |
| Nature of content: | Articolo in rivista/Article |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.fuproc.2014.09.042 |
| Appears in Collections: | 01 - Journal article |
Files in This Item:
| File | Description | Type | License | |
|---|---|---|---|---|
| Fuel Processing Technology 130 (2015) 78–86.pdf | N/A | Tutti i diritti riservati (All rights reserved) | Embargo Request a copy |
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