Melipona favosa (Fabricius, 1798) was the first stingless bee described as Apis favosa by the Danish zoologist Johan Christian Fabricius, who proposed the basis for modern insect classification since the 18th century. The Melipona Illiger, 1806 genus was described later. A sample of Erica M. favosa honey with a distinctive clove smell was collected between Moruy and Guacurebo, in a meliponary at the foothills of Santa Ana hill, Falcon Municipality, Falcon state, Venezuela. Until El Niño in 1999 only peninsular Erica honey was produced before the arrival of Africanized bees. The abundance of volatile organic compounds (VOCs) of this honey was studied in triplicates by head space-solid phase microextraction (HS-SPME) and gas chromatography coupled to mass spectrometry (GCMS). A set of 63 VOCs were detected consisting of 14 acids, 13 alcohols, 6 aldehydes, 10 esters, 7 ketones, 2 monoterpenes, 4 oxides, and 7 unknown compounds. The most abundant were cis linalool oxide, trans linalool oxide, and acetic acid. The VOC that smells like clove was not identified. It is clearly not eugenol, but may be an unknown compound from another plant. It is ruled out that it is contamination, but here is a documented case study: In pasteurized orange juice, the formation of the clove-like odorant 5-vinylguaiacol originated after residues of the cleaning agent peracetic acid reacted with the natural orange flavonoid hesperidin after heating

Betta, E.; Vit, P.; Vit, D.; Vit, L.; Reschini, A.; Meccia, G.; Biasioli, F. (2024). Perfil de volátiles por CG-EM de una miel de Erica Melipona favosa que huele a clavo de olor es producida en la Península de Paraguaná, estado Falcón, Venezuela. In: Memorias del 2024 Simposio Internacional JMF Camargo sobre abejas sin aguijón, Mérida, Venezuela, June 26-29, 2024. Mérida, Venezuela: Editorial APIBA-ULA: 71. ISBN: 9789801846130. handle: https://hdl.handle.net/10449/85897

Perfil de volátiles por CG-EM de una miel de Erica Melipona favosa que huele a clavo de olor es producida en la Península de Paraguaná, estado Falcón, Venezuela

Betta, E.
Primo
;
Biasioli, F.
Ultimo
2024-01-01

Abstract

Melipona favosa (Fabricius, 1798) was the first stingless bee described as Apis favosa by the Danish zoologist Johan Christian Fabricius, who proposed the basis for modern insect classification since the 18th century. The Melipona Illiger, 1806 genus was described later. A sample of Erica M. favosa honey with a distinctive clove smell was collected between Moruy and Guacurebo, in a meliponary at the foothills of Santa Ana hill, Falcon Municipality, Falcon state, Venezuela. Until El Niño in 1999 only peninsular Erica honey was produced before the arrival of Africanized bees. The abundance of volatile organic compounds (VOCs) of this honey was studied in triplicates by head space-solid phase microextraction (HS-SPME) and gas chromatography coupled to mass spectrometry (GCMS). A set of 63 VOCs were detected consisting of 14 acids, 13 alcohols, 6 aldehydes, 10 esters, 7 ketones, 2 monoterpenes, 4 oxides, and 7 unknown compounds. The most abundant were cis linalool oxide, trans linalool oxide, and acetic acid. The VOC that smells like clove was not identified. It is clearly not eugenol, but may be an unknown compound from another plant. It is ruled out that it is contamination, but here is a documented case study: In pasteurized orange juice, the formation of the clove-like odorant 5-vinylguaiacol originated after residues of the cleaning agent peracetic acid reacted with the natural orange flavonoid hesperidin after heating
Melipona favosa (Fabricius, 1798) fue la primera abeja sin aguijón descrita como Apis favosa por el zoólogo danés Johan Christian Fabricius, quien propuso las bases para la clasificación moderna de insectos desde el siglo XVIII. El género Melipona Illiger, 1806 se describió más tarde. Una muestra de miel de Erica Melipona favosa con un particular olor a clavo de olor fue recolectada entre Moruy y Guacurebo, en un meliponario al pie de la sierra de Santa Ana, Municipio Falcón, estado Falcón, Venezuela. Hasta El Niño de 1999 sólo se producía miel de Erica peninsular hasta la llegada de las abejas africanizadas. La abundancia de compuestos orgánicos volátiles (COVs) de esta miel se estudió por triplicado mediante espacio de cabezamicro extracción en fase sólida (EC-MEFS) y cromatografía de gases acoplada a espectrometría de masas (GC-EM). Se detectó un conjunto de 63 COVs conformado por 14 ácidos, 13 alcoholes, 6 aldehídos, 10 ésteres, 7 cetonas, 2 monoterpenos, 4 óxidos, y 7 compuestos desconocidos. Los más abundantes fueron el óxido de cis linalol, el óxido de trans linalol y el ácido acético. No se indentificó el COV que huele a clavo de olor. Claramente, no es eugenol, pero puede ser un compuesto desconocido de otra planta. Se descarta que sea contaminación, pero a continuación un caso documentado: En el jugo de naranja pasteurizado, la formación del 5-vinilguaiacol que huele a clavo de olor se originó cuando los residuos del agente limpiador ácido peracético reaccionaron con el flavonoide natural de la naranja hesperidina
Honey
Melipona favosa
Paraguana Peninsula
Volatile Organic Compounds (VOCs)
Miel
Melipona favosa
Península de Paraguaná
Compuestos orgánicos volátiles
9789801846130
2024
Betta, E.; Vit, P.; Vit, D.; Vit, L.; Reschini, A.; Meccia, G.; Biasioli, F. (2024). Perfil de volátiles por CG-EM de una miel de Erica Melipona favosa que huele a clavo de olor es producida en la Península de Paraguaná, estado Falcón, Venezuela. In: Memorias del 2024 Simposio Internacional JMF Camargo sobre abejas sin aguijón, Mérida, Venezuela, June 26-29, 2024. Mérida, Venezuela: Editorial APIBA-ULA: 71. ISBN: 9789801846130. handle: https://hdl.handle.net/10449/85897
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