Sesquiterpenes are an important class of molecules, with roles ranging from pollination and signalling to defense mechanisms. Despite their apparent importance, the limited number of commercial standards has hindered their study and precise quantification. Herein, we report the syntheses of fourteen labelled sesquiterpenes with a high level of deuterium incorporation (>95%) for applications in MS-based studies.

Duhamel, N.; Martin, D.; Larcher, R.; Fedrizzi, B.; Barker, D. (2016). Convenient synthesis of deuterium labelled sesquiterpenes. TETRAHEDRON LETTERS, 57 (40): 4496-4499. doi: 10.1016/j.tetlet.2016.08.079 handle: http://hdl.handle.net/10449/36583

Convenient synthesis of deuterium labelled sesquiterpenes

Larcher, Roberto;
2016

Abstract

Sesquiterpenes are an important class of molecules, with roles ranging from pollination and signalling to defense mechanisms. Despite their apparent importance, the limited number of commercial standards has hindered their study and precise quantification. Herein, we report the syntheses of fourteen labelled sesquiterpenes with a high level of deuterium incorporation (>95%) for applications in MS-based studies.
Sesquiterpenes
Isotopic labelling
Deuterium
Terpenoids
Settore CHIM/06 - CHIMICA ORGANICA
Duhamel, N.; Martin, D.; Larcher, R.; Fedrizzi, B.; Barker, D. (2016). Convenient synthesis of deuterium labelled sesquiterpenes. TETRAHEDRON LETTERS, 57 (40): 4496-4499. doi: 10.1016/j.tetlet.2016.08.079 handle: http://hdl.handle.net/10449/36583
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