The synthesis of the low molecular weight sulfonic acids, 2-methyl-4-oxopentane-2-sulfonic acid, 1-hydroxyhexane-3-sulfonic acid, 1-oxohexane-3-sulfonic acid and 1-hydroxyhexane-1,3-disulfonic acid from trans-2-hexenal and ethyl hex-2-enoate is reported. These sulfonic acids are putative precursors to the important wine aroma thiols, 3-mercaptohexan-1-ol, 3-mercaptohexyl acetate and 4-mercapto-4-methylpentan-2-one

Duhamel, N.; Piano, F.; Davidson, S.J.; Larcher, R.; Fedrizzi, B.; Barker, D. (2015). Synthesis of alkyl sulfonic acid aldehydes and alcohols, putative precursors to important wine aroma thiols. TETRAHEDRON LETTERS, 56 (13): 1728-1731. doi: 10.1016/j.tetlet.2015.02.084 handle: http://hdl.handle.net/10449/24775

Synthesis of alkyl sulfonic acid aldehydes and alcohols, putative precursors to important wine aroma thiols

Larcher, Roberto;
2015-01-01

Abstract

The synthesis of the low molecular weight sulfonic acids, 2-methyl-4-oxopentane-2-sulfonic acid, 1-hydroxyhexane-3-sulfonic acid, 1-oxohexane-3-sulfonic acid and 1-hydroxyhexane-1,3-disulfonic acid from trans-2-hexenal and ethyl hex-2-enoate is reported. These sulfonic acids are putative precursors to the important wine aroma thiols, 3-mercaptohexan-1-ol, 3-mercaptohexyl acetate and 4-mercapto-4-methylpentan-2-one
Sulfonic acids
3-mercaptohexan-1-ol
4-mercapto-4-methylpentan-2-one
Wine thiols
Settore CHIM/10 - CHIMICA DEGLI ALIMENTI
2015
Duhamel, N.; Piano, F.; Davidson, S.J.; Larcher, R.; Fedrizzi, B.; Barker, D. (2015). Synthesis of alkyl sulfonic acid aldehydes and alcohols, putative precursors to important wine aroma thiols. TETRAHEDRON LETTERS, 56 (13): 1728-1731. doi: 10.1016/j.tetlet.2015.02.084 handle: http://hdl.handle.net/10449/24775
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10449/24775
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